Di-μ-sulfido-bis{[rac-1,2-bis(η5-4,5,6,7-tetrahydroinden-1-yl)ethane]zirconium(IV)} toluene monosolvate
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چکیده
منابع مشابه
Di-μ-sulfido-bis{[rac-1,2-bis(η5-4,5,6,7-tetrahydroinden-1-yl)ethane]zirconium(IV)} toluene monosolvate
The title dimeric zirconium complex, [Zr(2)(C(20)H(24))(2)S(2)]·C(7)H(8), was obtained from the reaction of (ebthi)Zr(η(2)-Me(3)Si-C(2)-SiMe(3)) [ebthi is rac-1,2-bis-(η(5)-4,5,6,7-tetra-hydro-inden-1-yl)ethane] and S=C=N-ada (ada = adamantan-1-yl) along with the formation of the isonitrile C N-ada. Each Zr(IV) atom is coordinated by the sterically hindered ebthi ligand and two μ-sulfide ligand...
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The title compound, {(C6H8N)[AgWSe4]·C6H7N} n , consists of anionic [WAgSe4] n chains, 2-methyl-pyridinium cations and neutral 2-methyl-pyridine mol-ecules. The Se atoms bridge the Ag and W atoms, forming a polymeric chain extending along the b-axis direction. Both the Ag and W atoms are located on a twofold rotation axis and each metal atom is coordinated by four Se atoms in distorted tetra-he...
متن کاملcatena-Poly[[tetrakis(hexamethylphosphoramide-κO)bis(nitrato-κ2 O,O′)dysprosium(III)] [molybdenum(VI)-di-μ-sulfido-silver(I)-di-μ-sulfido]]
Hexamethyl-phospho-ramide (hmp), tetra-thio-molybdate, silver sulfide and dysprosium nitrate were self-assembled to form an anionic [AgMoS(4)](n) (n-) chain in the title complex, {[Dy(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgMoS(4)]}(n). The central Dy atom in the cation is coordinated by eight O atoms from two nitrate and four hmp ligands, resulting in a distorted square-anti-prismatic environment. To...
متن کاملcatena-Poly[[tetrakis(hexamethylphosphoramide-κO)bis(nitrato-κ2 O,O′)holmium(III)] [silver(I)-di-μ-sulfido-tungstate(VI)-di-μ-sulfido]]
In the title salt, {[Ho(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgWS(4)]}(n), the anion forms a W/S/Ag polymeric chain along the a axis. The holmium atom in the cation is coordinated by eight O atoms from two nitrate and four hexa-methyl-phospho-ramide ligands in a distorted square-anti-prismatic geometry. Together with the two nitrate ligands, the complex cation in the title compound is univalent, whic...
متن کاملBis[4-(2-azaniumylethyl)piperazin-1-ium] di-μ-sulfido-bis[disulfidogermanate(II)]
In the title compound, (C(6)H(17)N(3))(2)[Ge(2)S(6)], the dimeric [Ge(2)S(6)](4-) anion is formed by two edge-sharing GeS(4) tetra-hedral units. The average terminal and bridging Ge-S bond lengths are 2.164 (2) and 2.272 (8) Å, respectively. The dimeric inorganic anions and the organic piperazinium cations are organized into a three-dimensional network by N-H⋯S hydrogen bonds.
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2012
ISSN: 1600-5368
DOI: 10.1107/s1600536812044121